Skip to content

Search the chemistry universe

Elements, molecules, concepts, simulations, experiments and pages.

Enter a formula, name or conceptFull search

States of matter

Heat an element and watch it change state — or skip a state entirely.

SchoolLive

Scientific learning path

  1. 01UnderstandLive
  2. 02ExploreLive
  3. 03ExperimentLive
  4. 04ObserveLive
  5. 05ExplainLive
  6. 06ApplyLive
  7. 07TestBuilding
Explanation mode
SolidGasSublimation887 K0 K1472 K

How the particles sit

Try one

All figures at one atmosphere

Description of this simulation

At 589 K and one atmosphere, Arsenic is a solid. Arsenic has no liquid state at this pressure at all: its solid turns straight to vapour at 887 K, below the 1090 K it would need to melt. That is sublimation, and it is why the two numbers look the wrong way round.

AsArsenic

State at this temperature

Solid

Fixed neighbours in a lattice, vibrating in place. A solid keeps its shape.

Sublimes at
887 K614 °C
Liquid over
No liquid state at this pressure

Sublimation

The boiling point of this element is below its melting point, which is not an error. Its solid reaches a vapour pressure of one atmosphere before it gets hot enough to melt, so at this pressure it turns straight to vapour and has no liquid state at all.

Why there is no pressure control

A phase diagram needs a vapour-pressure curve for every substance on it. The reference set carries melting and boiling points at one atmosphere only, so a pressure axis would mean drawing a boundary nobody measured. It is left out rather than invented.

What this model shows — and what it simplifies

Educational Model

Melting and boiling points are the published values at one atmosphere, and the state at any temperature is read off them rather than modelled.

Where do we see this in real life?

Dry ice sublimes rather than melting, which is why it leaves no puddle. Freeze-drying uses the same trick on food, and tungsten is chosen for furnace parts and lamp filaments because it stays solid to 3695 K.