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Solutions and concentration

Make it up to the mark, then dilute it and watch the moles stay put.

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Explanation mode
250 mL
Mass to weigh out
1.461 g
Amount
0.0250 mol
Concentration
0.100 mol/L

Per litre of solution, not of solventDissolve the solute first, then make the volume up to the mark. Adding a litre of water to the solute gives a different concentration, because the solute takes up room of its own.

Dilution

c₁V₁ = c₂V₂

Give any three and the fourth follows.

Starting concentration

1.000mol/L

Starting volume

50mL

Final concentration

0.100mol/L

Final volumeSolve for

500 mL

Moles before: 0.05000Moles after: 0.05000Times more dilute: 10.00×Solvent added: 450 mL

Unchanged — dilution conserves moles, not volume.

Description of this simulation

1.461 g of NaCl dissolved and made up to 0.25 L of solution is 0.1 mol/L. That is 0.025 moles in 0.25 litres. The volume is the volume of the finished solution, not the volume of solvent added — the solute takes up room of its own, so the two are not the same thing. Starting with 0.05 L of 1 mol/L NaCl and making it up to 0.5 L gives 0.1 mol/L — 10 times more dilute. Adding 0.45 L of solvent changed the volume and changed nothing about the amount of solute: there were 0.05 moles before and there are 0.05 moles after. Dilution conserves moles, not volume.

Molar mass

58.440

g/mol

How that molar mass is built

  • Na1 × 22.99022.99
  • Cl1 × 35.45035.45

The same solution, other ways

Mass per litre
5.84 g/L
Percent mass/volume
0.584 %
Parts per million
5,844 ppm

Milligrams per litre equals parts per million only because a litre of dilute aqueous solution weighs very nearly a kilogram.

What this model shows — and what it simplifies

Educational Model

Molar masses are computed from the standard atomic weights in the element table, so they agree with the periodic table by construction rather than by a second copy being kept in step.

Where do we see this in real life?

A saline drip is 0.9 per cent sodium chloride because that matches the concentration inside a cell. A little either way and the cells swell or shrivel — which is why the arithmetic on this page is done carefully in every hospital pharmacy.